编辑: ok2015 | 2015-06-02 |
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12 -- Section 3: Composition/information on ingredients 3.1 Substance information Substance name CAS No. EC No. Index No. Classification according to DSD Classification according to CLP % (w/w) Glyoxylic acid 298-12-4 206-058-5 Not listed. Xi;
R41 - Xi;
R43 Met. Corr. 1;
H290 Eye Dam. 1;
H318 Skin Sens. 1;
H317 ≥
50 Water 7732-18-5 231-791-2 Not listed. Not classified. Not classified. ≤
48 Remark: The rest unspecified ingredients are impurities, and they do not influence classification and labeling of the product. Full text of R-phrase(s) and H-statement(s): see section 16. Section 4: First aid measures 4.1 Description of first aid measures General notes: In all cases of doubt, or when symptoms persist, seek medical attention. Following inhalation: If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. Following skin contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. Following eye contact: Rinse thoroughly with plenty of water for at least
15 minutes and consult a physician. Continue rinsing eyes during transport to hospital. Following ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Notes for the doctor: Treat symptomatically and supportively. Treatment may vary with condition of victim and specifics of incident. 4.2 Most important symptoms and effects, both acute and delayed Potential Health Effects Inhalation May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Skin May be harmful if absorbed through skin. Causes skin burns. Eyes Causes eye burns. Ingestion May be harmful if swallowed. Causes burns. 山东中蓝化工有限公司 ZHONGLAN INDUSTRY CO.,LTD. ADD: 7/F SANQING FENGRUN BLDG,NO.100 SOUTH GONGYE ROAD, JINAN CITY, CHINA.P.C.:250100 TEL:86-531-82956570 Email ID: [email protected] -- Page
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12 -- 4.3 Indication of the immediate medical attention and special treatment needed Persons with pre-existing skin, eye, or respiratory disease may be at increased risk from the irritant or allergic properties of this material. Attending physician should treat exposed patients symptomatically. Section 5: Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media: Dry chemical, carbon dioxide or water spray. Unsuitable extinguishing media: Avoid direct contact between water and acid. 5.2 Special hazards arising from the substance or mixture Substance is combustible. may burn but does not ignite readily. Inspect the electrical fittings regularly against the higher risk of corrosion. When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Fire may produce irritating, corrosive and/or toxic gases. 5.3 Advice for fire-fighters Do not stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing. Section 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and material for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust) Prevent product from entering drains. Keep in suitable and closed containers for disposal. Do not flush into surface water or sanitary sewer system. 山东中蓝化工有限公司 ZHONGLAN INDUSTRY CO.,LTD. ADD: 7/F SANQING FENGRUN BLDG,NO.100 SOUTH GONGYE ROAD, JINAN CITY, CHINA.P.C.:250100 TEL:86-531-82956570 Email ID: [email protected] -- Page