PDF《He Fu （付赫） candidate for Ph. D.》

He Fu (付赫) candidate for Ph.

D. Room A909, New Chemistry Building, Peking University,

100871 Tel: (+86) 138-1046-3873 E-mail: hefu@pku.edu.cn Objective R&

D Education 2011.9Cpresent Peking Univ. Materials Chemistry Ph.D. Candidate (Expected graduation: 2016.7) 2007.9C2011.7 Peking Univ. Materials Chemistry Bachelor of Science Research Experiences 2015.6Cpresent 2012.9Cpresent 2012.9C2013.9 2010.9C2012.9 2008.9Cpresent Ionic Liquid-mediated Nanoconfinement of Borohydrides Topic Leader ? Synthesized CMK-5, graphene tube and ZIF-8 derived porous carbons materials as substrate for nanoconfinement of borohydrides. Synthesized well-dispersed borohydride-porous carbon composites using ionic liquids as media. ? Investigated the hydrogen storage properties and mechanism of the composites. Modified the Thermodynamics of Borohydrides for Hydrogen Storage Topic Leader ? Analyzed thermodynamic issues in borohydrides. Proposed a novel approach to modulate the dehydrogenation enthalpy via the introduction of ionic liquids. ? Synthesized bmimNTf2, bmmimNTf2 and bmimBH4;

incorporated with borohydrides. ? Characterized the properties by using TPD/MS, DSC and TG. Achieved low desorption temperature, reversed thermodynamics and state-of-the-art performances. ? Investigated the mechanism by using

11 B/1 H NMR, FT-IR and XRD. Proposed a synergetic mechanism of conjugate cation induced dehydrogenation and ionic liquid-assisted thermodynamic modulation. Synthesized Key Intermediates in the Desorption of Borohydrides Topic Leader ? Synthesized triborane(8) compounds via a novel reaction between amalgam and borane-THF. Discover their capability as hydrogen storage materials. ? Mastered the Schlenk'

s techniques for air- and moisture-sensitive metal-organic reactions. Synthesized Novel B-N-based Hydrogen Storage Compounds Topic Leader ? Synthesized Li-derivative of hydrazine bisborane using n-BuLi and hydrazine bisborane. Investigated its structure and dehydrogenation properties by using XRD, NMR, TPD/MS, DSC and Sievert-type apparatus. ? Designed a home-made apparatus to synthesize Li- and Mg- derived hydrazine bisborane ammoniates. Participated in some collaborative researches Co-worker ? Acted as a collaborator in a wide range of researches, including the design of ORR/OER/HER catalysts, investigation on hydrogen (de)sorption feature of MOFs, novel anode materials for Li-ion batteries (hydrogen storage material), purification of rare-earth metals, preparation of nanoparticles using thermal plasma, etc. Academic Activities 2014.7 The 14th International Symposium on Metal-Hydrogen Systems Poster Manchester, UK ? The MH meeting is most influential international conference in the field of hydrogen energy. The title of poster presentation is Synthesis of LiNH(BH3)NH2BH3 as a Hydrogen Storage Material . 2012.10 The 13th International Symposium on Metal-Hydrogen Systems Poster Kyoto, Japan ? The title of poster presentation is In situ hybridization of LiNH2CLiHCMg(BH4)2 nano-composites for enhanced hydrogen storage properties . 2013C2015 The 2nd to 4th Doctorial Symposium on Hydrogen Energy Oral China ? The doctorial symposium provides a platform for Ph. D. students in China to communicate, share and discuss with each other. I was invited as oral presentation for three years in a row. 2011.12 Exchange Program in Japan, Korea, Europe and China Oral Sasebo, Japan ? This exchange program was hosted by Sasebo National College of Technology. It provides a platform for students in Japan, Korea, Europe and China to discuss in energy related topics, including the future of nuclear energy after the Great Earthquake in Japan, the smart grid, and renewable energy. The title of my oral presentation is The Great East Japan Earthquake and Fukushima Nuclear Accident -- A Preliminary Review . Extra-curricular Experiences 2015.8 The 6th International Symposium on Plasma Nanosciences Volunteer (Register) 2013.7 The 7th National Coordination Chemistry Conference Volunteer (VVIP service) 2012.9C2014.9 Class tutor of undergraduates in CCME, Peking University Undergraduate Affairs 2012.5 The 1st Doctorial Symposium on Hydrogen Energy Organizer (General) Awards