PDF《中国科学院大连化学物理研究所》

中国科学院大连化学物理研究所 优秀博士后奖励基金申请表 申请人: Joby Sebastian 研究组:

1508 学科专业: Biomass Conversion 合作导师:Dr.

Zheng Mingyuan &

Prof. Zhang Tao 填表日期:

2016 年11 月5日中国科学院大连化学物理研究所制

1 姓名Joby Sebastian 性别Male 出生日期 1984-11-30 民族Indian 学历/学位 Doctor 专业技术职务 / 毕业院校 Academy of Scientific and Innovative Research (AcSIR), India. 专业Chemical Sciences (拟)入站时间 2016-07-24 入站性质 统招统分 在职人员 E-Mail sebastian@dicp.ac.cn 联系电话

150 4242

2379 学习简历 起止年月 所在单位/专业 所获学位 2002-2005 Mahatma Gandhi University, Kerala, India/ Chemistry Bachelor of Science 2005-2007 Mahatma Gandhi University, Kerala, India/ Chemistry Master of Science 2008-2010 Cochin University of Science and Technology, Kerala, India/ Industrial Catalysis Master of Technology 2010-2015 Academy of Scientific and Innovative Research, India/ Chemical Sciences Doctor of Philosophy 工作经历 起止年月 所在单位 职务 NA NA NA 博士 学位 论文 摘要 博士论文题 目Catalytic Activity Study of Double-Metal Cyanide Complexes for Biodegradable Polymers Synthesis 指导教师姓 名Prof. Dr. Darbha Srinivas CSIR-National Chemical Laboratory, Pune-411008, India

2 (限800 字) The main objective of the thesis was to unravel the critical structural and compositional features of catalysts responsible for their activity and selectivity in polymers synthesis through structure-activity correlations. The studied biodegradable polymers (polycarbonates and hyperbranched polyesters) are commercially well-known and categorized as bulk and speciality chemicals. Lewis acidity, micro/meso porosity and surface hydrophobicity are the main features of Fe-Zn double metal catalyst (DMC) that favoured good activity and selectivity in hyperbranched polyesters synthesis. Catalyst crystal symmetry, Lewis acidity, complexing agent, halogen and alkali metal content are the decisive parameters that controlled activity of Co-Zn DMCs in polycarbonate synthesis. The attempted studies greatly contribute towards the rational design of efficient DMC catalysts for said polymers synthesis. 入站前期科 研情况简介

1、主持或参与项目情况: 序号 项目名称 项目来源 项目金额 起止年度 角色 NA NA NA NA NA

2、论文发表情况: 序号 论文题目 期刊名 影响因子 发表年度/卷期/页码排序

1 Factors influencing the catalytic activity of of Co-Zn double-metal cyanide complexes for alternating polymerization of epoxides and CO2 Applied Catalysis A: General 4.012 2015, 506, 163-172 Ist 2. Structure-induced catalytic activity of Co-Zn double-metal cyanide complexes for terpolymerization of propylene oxide, cyclohexene oxide and CO2 RSC Advances 3.289 2015, 5, 18196-18203 Ist 3. Effects of method of preparation on catalytic activity of Co-Zn double-metal cyanide catalysts for copolymerization of CO2 and epoxide Applied Catalysis A: General 4.012 2014, 482, 300-308 Ist

3 4. Solid, double-metal cyanide catalysts for the synthesis of hyperbranched polyesters and aliphatic polycarbonates Journal Chemical Sciences 1.085 2014, 126, 499-509 Ist 5. Influence of of method of preparation of solid, double-metal cyanide complexes on their catalytic activity for synthesis of hyperbranched polymers Applied Catalysis A: General 4.012 2013, 464, 51-60 Ist 6. Novel application of a Fe-Zn double-metal cyanide catalyst in the synthesis of biodegradable, hyperbranched polymers Chemical Communications 6.567 2011, 47, 10449-10451 Ist 7. Double-metal catalyst design in CO2/epoxide polymerization Sustainable Polymers from Biomass, Wiley Book Chapter Ist