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N‰al?girSO20NOx)?~O3??Yt T(uCaSO34l?`nm?m8T6e ??S?Q\?pl-NSO20NOx?v+T?'0O3'lS?pl-NSO20NOx?v;

N‰?S"^?vípSf[?e z_:N NO(g) ?O3(g)===NO2(g) ?O2(g) "H? ?200.

9 kJ・mol ?1 NO(g) ?O2(g)===NO2(g)0"H? ?58.2 kJ・mol ?1 SO2(g) ?O3(g)===SO3(g) ?O2(g) "H? ?241.6 kJ・mol ?1 (1)?S"^3NO(g) ?O3(g)===3NO2(g)?v"H?kJ・mol ?10 (2)¤[)n N ?úV?[?eQ?S"^hV?vNO0SO2?vir(?v?' ?9e?S?ReQO3?vir(?v?' ??S"^N?k?e?? TSO?|-Nn(NO)0n(NO2)?Tn(SO2)C?S"^MRn(O3)6"n(NO)?v?SS?‰ N?V0 `$S_n(O3)6"n(NO)?1?e ??S"^ TNO2?vir(?v?'?Q\ ?vQ?SàV/f_0 a$?X?Rn(O3) ?O3'lSSO2?v?S"^àQNN N*Sq_?T ?vQ?S???SàV/f_0 (3)S_(uCaSO34l?`nm?m8T6e?~O3??Yt?v?pl?e ?n?m(pH?~:N8)-NSO\NO2lS:NNO ?vQ?yP[?e z_:N_0 ?‰g?(1)"^(u?v?e?[?_?L??‰T{0 (2)`$O3?v'lS'`?_:_ ?O3??\NO2'lS:N?f??÷N?v.l'lSir0 a$O3??'lSSO2 ? ??X?Rn(O3)?eO3'lSSO2?v?S"^àQNN N*Sq_?T ?vQ?SàV/fSO2 NO3?v?S"^?sba0 (3)NO2lS:NNO/fNO2?Su?N??S?S"^ ?RSO?Su'lS?S"^?pH?8?v?n?mHT±x'`0(WdkúW@x N ?"^(ufN?Q'lS??S?S"^?W?yP[?e z_?v?‰R ??S?QúQSO NNO2?S"^?v?yP[?e z_0 T{Hh?(1) ?317.3 (2)`$O3\NO2'lS:N?f??÷N.l'lSir(bub?NN2O5) a$SO2 NO3?v?S"^?sba (3)SO ?2NO2 ?2OH ?===SO ?2NO ?H2O

2 ?÷xów/fn?lu§N÷xx''cúQ?v?]N?^#n ?;

N‰bR/fCaSO4・2H2O0 (1)CaSO4・2H2O14l?S"^?vsQ?vípSf[?e z_?Y N? CaSO4・2H2O(s)===CaSO4・H2O(s) ?H2O(g)0"H1? ?83.2 kJ・mol ?1 CaSO4・2H2O(s)===CaSO4(s) ?2H2O(l)0"H2? ?26 kJ・mol ?1 H2O(g)===H2O(l)0"H3? ?44 kJ・mol ?1 R?S"^CaSO4・H2O(s)===CaSO4(s) ?H2O(g)?v"H4?kJ・mol ?10 (2)(u N T?v??SBR?S?N\CaSO4??S ?@b―_SO2?S(u?N?]Nu§Nkxx'0 `$?NCO\O??SBR ?9e?S?S"^)n?^?S―_0R N T?v§Nir0 N T)n?^ N?S"^ T@b―_úVSObR?vir(?v?'?Y?V1@b:y0(WNO?N800 !?e;

N‰??S§Nir:N_??N800 !?eCaS?Q\?v?SàV/f_ uSf[?e z_h?:y)0 a$?N??kxdq:N??SBRq?p2.5 h ? N Tag?Nù[kxx'?"lS?s?vq_?T?Y?V2@b:y0CaCl2?v\O(u/f_ S_)n?^???N1

200 !?e ?àe?? gàeCaCl2X[(W ?CaSO4?vlS?s??N?v T ?vQ?SàV/f_

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