PDF《data reports》

molecular graphics: ORTEP-3 for Windows (Farrugia, 2012);

software used to prepare material for publication: SHELXL97. Acknowledgements Whittier College is acknowledged for the funds that supported this research. Tammy Le is acknowledged for obtaining the data reports m164 Pen ?aloza et al. doi:10.1107/S2056989015014851 Acta Cryst. (2015). E71, m164Cm165 ISSN 2056-9890 UVCVis spectrum of the title compound. The upgrade of the diffractometer was made possible by grant No. LEQSF(2011C 2012)-ENH-TR-01, administered by the Louisiana Board of Regents. Supporting information for this paper is available from the IUCr electronic archives (Reference: WM5193). References Bruker (2014). SAINT, APEX2 and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA. Comerlato, N. M., Crossetti, G. L., Howie, R. A., Tibultino, P. C. D. &

Wardell, J. L. (2001). Acta Cryst. E57, m295Cm297. Dyakonenko, V. V., Zholob, O. O., Orysyk, S. I. &

Pekhnyo, V. I. (2015). Acta Cryst. E71, m10Cm11. Ettedgui, J. &

Neumann, J. (2009). J. Am. Chem. Soc. 131, 4C5. Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849C854. Johnson, L. K., Killian, C. M. &

Brookhart, M. (1995). J. Am. Chem. Soc. 117, 6414C6415. Kubota, M., Covarrubias, D., Pye, C., Fronczek, F. R. &

Isovitsch, R. (2013). J. Coord. Chem. 66, 1350C1362. Popeney, C. &

Guan, Z. (2005). Organometallics, 24, 1145C1155. Price, J. H., Williamson, A. N., Schramm, R. F. &

Wayland, B. B. (1972). Inorg. Chem. 11, 1280C1284. Sheldrick, G. M. (2008). Acta Cryst. A64, 112C122. Wang, L., Luo, X., Gao, B., Wu, Q. &

Mu, Y. (2012). Acta Cryst. E68, o128. Zhao, Y., Yuan, J., Zhao, J. &

Zhao, S. (2015). Acta Cryst. E71, o251Co252. data reports Acta Cryst. (2015). E71, m164Cm165 Pen ?aloza et al. [PdCl2(C28H24N2)]?CH4O m165 supporting information sup-1 Acta Cryst. (2015). E71, m164Cm165 supporting information Acta Cryst. (2015). E71, m164Cm165 [https://doi.org/10.1107/S2056989015014851] Crystal structure of [N,N′-bis(4-methylphenyl)-1,2-diphenylethane-1,2-diimine- κ2 N,N′]dichloridopalladium(II) methanol monosolvate Alfredo Pe?aloza, Frank R. Fronczek and Ralph Isovitsch S1. Synthesis and crystallization 0.086 g (0.257 mmol,

1 eq.) of PdCl2(DMSO)2 and 0.100 g (0.257 mmol,

1 eq.) of N,N′-di(4-methylphenyl)-1,2-diphenyl- ethane-1,2-diimine were combined with

10 ml of methanol and stirred for 1.5 hours at room temperature. The orange precipitate that formed was collected via vacuum filtration, washed well with water and then air-dried giving 0.0363 g (25%) of the title compound. Slow evaporation of the reaction mixture gave X-ray quality crystals of the title compound. MP: >

532 K. IR (KCl): 3135, 2922,

1514 cm-1 . UV-Vis (λ nm (ε)):

242 (41,200),

264 (34,800),

317 (17,800). TLC (alumina, ethanol): Rf = 0.59. S2. Refinement H atoms were........