编辑: 865397499 2013-06-20

9 7

7 6 期 郭小汾等 :钙化合物的种类对脱氯特性的影响 图8氢氧化钙与聚氯乙烯共燃烧的灰分 XRD 分析结果 Fig.

8 XRD of ash of Ca(OH)

2 + PVC combustion ( + ― CaO ,

3 ― CaCl2) 图9碳酸钙与聚氯乙烯共燃烧灰分的 XRD 分析结果 Fig.

9 XRD of ash CaCO3 + PVC combustion ( + ― CaO ,

3 ― CaCl2)

3 结论

11 用PVC 作为氯化氢的释放源是可行的.

21 三种钙化物中氢氧化钙的脱氯效果最好.

31 氧化钙与氢氧化钙的脱氯机理基本相似.

41 各种钙化物在不同气氛下的脱氯机理是不同的.

51 燃烧状态下 ,在高温段钙化物脱氯产物氯化钙有分解迹象. 参考文献 : [

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4 ] Daoudi W ,Walters J K. A thermogravimetric study of the reactin of hydrogen chloride gas with calcined limestone :determi2 nation of kinetic parameters[J ]. Chemical Engineering Journal ,1991 ,47 :1 ―

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5 ] Daoudi W ,Walters J K. The reaction of HCl gas with calcined commercial limestone particles :the effect of particle size[J ]. Chem Eng J ,1991 ,47 :11 ―

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6 ] Duo W , Kirkby N F ,Seville J P K, et al. Alteration with Reaction Progress of The Rate limiting step for solid2gas reactions of ca2compounds with HCl[J ]. Chemical Engineering Science ,1995 ,50(13) :2017 ―

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7 ] Duo W ,Seville J P K, Kirkby N F , et al. Formation of product layers in solid2gas reactions for removal of acid gases[J ]. Chemical Engineering Science ,1994 ,49(24A) :4429 ―

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8 ] Duo W , Kirkby N F ,Seville J P K, et al. Kinetics of HCl reactions with calcium and sodium sorbents for IGCC fuel gas cleaning[J ]. Chemical Engineering Science ,1996 ,51(11) :2541 ―

2546 0

8 7 环境科学学报20 卷 ........

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