PDF《Metal Phosphates》

Addition and Correction to Complete Field Guide to Asymmetric BINOL-Phosphate Derived Br?nsted Acid and Metal Catalysis: History and Classi?cation by Mode of Activation;

Br?nsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates Dixit Parmar, Erli Sugiono, Sadiya Raja, and Magnus Rueping* Chem.

Rev.2014,

114 (18), 9047. DOI: 10.1021/cr5001496 The authors provide the following corrections, additions, and amendments. Figure 59: The corrected transition state indicating a 1,4-addition is shown below: Figure 73: The proposed catalyst/substrate interaction shown in Figure

73 corresponds to the related sulfoxidation catalyzed by chiral phosphoric acid PA

5 (ref 133). Please note that this interaction will be di?erent for PA 43. Figure

105 and surrounding text: The asymmetric reduction was achieved with

1 mol % (S)-PA

25 (ref

195 ). Figure

176 and surrounding text: For the ?rst example of the application of asymmetric counteranion directed catalysis with phosphoric acid salts as catalysts, see ref 29d. Figure 192: The proposed transition state corresponds to the spiroacetalization catalyzed by chiral phosphoric acid (S)-PA

25 (ref 373). Please note that this will be di?erent for PA 43. Figure 196: The correct substrate used is TMSN3. Please note that an alternative mechanism has been proposed (ref 381), as discussed in the surrounding text. Figure 228: The correct structure of

427 is Figure 257: The correct con?guration of the diamine ligand used is shown below. For mechanistic studies, see ref 476c. REFERENCES (1) (a) Taylor, M. S.;

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