PDF《Sorption ratio》

10 MPa

6 Al(OH)(BDC-NH2)d (NH2-MIL-53) 1.0c negligible >

10 283 K,

100 kPa

7 Cu3(BTC)2 (HKUST-1)e

284 98 2.9

298 K, 1.5 MPa

8 Zn(nbIm)(nIm) (ZIF-78)f

50 13 3.8

298 K,

100 kPa

9 Zn2(BBA)2(CuPyen)g

10 2.9 3.4

295 K,

100 kPa

10 Mn(HCOO)2

100 10

10 195 K,

100 kPa

11 [Zn7O2(BDC-NO2)5(DMF)]e,h 8.8 4.4

2 195 K,

100 kPa

12 [Zn2(sdb)2(bpy)2]i

28 negligible >

10 195 K,

100 kPa

13 [Zn2(sdb)2(dabco)2]i,j

65 35 1.9

195 K,

100 kPa

13 (Me2NH2)In(NH2BDC)2 d

170 negligible >

10 298 K,

3 MPa

14 Cu(BDC-OH)(4,4'

-bpy)d,i

30 5.0 6.0

296 K,

100 kPa

15 Cu6(PDC)6 k

65 18 3.6

296 K,

100 kPa

16 [Cu(dpa)2(SiF6)]l 238m 7.5m

12 298 K,

100 kPa

17 [Zr6O4(BDC)6] (UiO-66)d 5.6c 3.2c 1.8

306 K, 2.5 MPa

18 UiO-66-COOH 6.4c 2.7c 2.0

306 K, 2.5 MPa

18 [Y2(TPBTM)(H2O)2]n

130 30 4.3

273 K,

100 kPa

19 3 4,4'

-sulfonyldibenzoate, bpy = 4,4'

-bipyridine, j dabco = 1,4-diazabicyclo[2,2,2]octane, k PDC = 3,5-pyridine-dicarboxylate, l dpa = 4,4'

dipyridylacetylene, m amount of sorption is mg g-1 , n TPBTM = N,N'

,N'

'

-tris(isophthalyl)-1,3,5-benzenetricarboxamide. [1] D. Saha, Z. Bao, F. Jia, S. Deng, Environ. Sci. Technol., 2010, 44, 1820. [2] S. U. Rege, R. T. Yang, M. A. Buzanowski, Chem. Eng. Sci., 2000, 55, 4827. [3] X. Liu, J. Li, L. Zhou, D. Huang, Y. Zhou, Chem. Phys. Lett., 2005, 415, 198. [4] C. A. Grande, R. Blom, A. M?ller, J. M?llmer, Chem. Eng. Sci., 2013, 89, 10. [5] C. Volzone, J. Ortiga, Process Saf. Environ., 2004, 82, 170. [6] S. Bourrelly, P. L. Llewellyn, C. Serre, F. Millange, T. Loiseau, G. Férey, J. Am. Chem. Soc., 2005, 127, 13519. [7] S. Couck, E. Gobechiya, C. E. A. Kirschhock, P. Serra-Crespo. J. Juan-Alca?iz, A. M. Joaristi, E. Stavitski, J. Gascon, F. Kapteijn, G. V. Baron, J. F. M. Denayer, Chem. Sus. Chem. 2012, 5, 740. [8] Z. Liang, M. Marshall, A. L. Chaffee, Energy &

Fuels, 2009, 23, 2785. [9] R. Banerjee, H, Furukawa, D. Britt, C. Knobler, M. O'

Keeffe, O. M. Yaghi, J. Am. Chem. Soc. 2009, 131, 3875. [10] Z. Zhang, S. Xiang, K. Hong, M. C. Das, H. D. Arman, M. Garcia, J. U. Mondal, K. M. Thomas, B. Chen, Inorg. Chem. 2012, 51, 4947. [11] D. N. Dybtsev, H. Chun, S. H. Yoon, D. Kim, K. Kim, J. Am. Chem. Soc. 2004, 126, 32. [12] S. S. Iremonger, R. Vaidhyanathan, R. K. Mah, G. K. H. Shimizu, Inorg. Chem. in press. [13] Y. Hijikata, S. Horike, M. Sugimoto, M. Inukai, T. Fukushima, S. Kitagawa, Inorg. Chem., 2013, 52, 3634. [14] S. Biswas, J. Zhang, Z. Li, Y. Y. Liu, M. Grzywa, L. Sun, D. Volkmer, P. Van Der Voort, Dalton. Trans. 2013, 42, 4730. [15] Z. Chen, S. Xiang, H. D. Arman, J. U. Mondal, P. Li, D. Zhao, B. Chen, Inorg. Chem., 2011, 50, 3442. [16] H. Xu, Y. He, Z. Zhang, S. Xiang, J. Cai, Y. Cui, Y. Yang, G. Qian, B. Chen, J. Mater. Chem. A, 2013, 1, 77. [17] P. Nugent, Y. Belmabkhout, S. D. Burd, A. J. Cairns, R. Luebke, K. Forrest, T. Pham, S. Ma, B. Space, L. Wojtas, M. Eddaoudi, M. J. Zaworotko, Nature, 2013, 495, 80. [18] M. Lin Foo, S. Horike, T. Fukushima, Y. Hijikata, Y. Kubota, M. Takata, S. Kitagawa, Dalton. Trans., 2012, 41, 13791. [19] K. Tang, R. Yun, Z. Lu, L. Du, M. Zhang, Q. Wang, H. Liu, Cryst. Growth Des. 2013, 13, 1382.

4 Table S3. Amounts of C2H4 and C2H6 sorption [cm3 g-1 at stp] and sorption ratios of various materials a amount of sorption is mol mol-1 , b amount of sorption is wt%, c amount of sorption is mmol g-1 d sdb = 4,4'

-sulfonyldibenzoate, bpy = 4,4'

-bipyridine, e dabco = 1,4-diazabicyclo[2,2,2]octane, f H8L = 1,2,4,5-tetra(5-isophthalic acid)benzene, DMA = N,N'